Publication Abstracts
Ma et al. 2011
, R.H. TIpping, and N.N. Lavrentieva, 2011: Pair identity and smooth variation rules applicable for the spectroscopic parameters of H2O transitions involving high-J states. Molec. Phys., 109, 1925-1941, doi:10.1080/00268976.2011.599343.
Two basic rules (i.e. the pair identity and the smooth variation) applicable for H2O transitions involving high-J states have been discovered. The origins of these rules are the properties of the energy levels and wavefunctions of H2O states with the quantum number J above certain boundaries. As a result, for lines involving high-J states in individually defined groups, all their spectroscopic parameters (i.e. the transition wavenumber, intensity, pressure-broadened half-width, pressure-induced shift, and temperature exponent) must follow these rules. One can use these rules to screen spectroscopic data provided by databases and to identify possible errors. In addition, by using extrapolation methods within the individual groups, one is able to predict the spectroscopic parameters for lines in this group involving very high-J states. The latter are required in developing high-temperature molecular spectroscopic databases such as HITEMP.
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BibTeX Citation
@article{ma00800v, author={Ma, Q. and TIpping, R. H. and Lavrentieva, N. N.}, title={Pair identity and smooth variation rules applicable for the spectroscopic parameters of H2O transitions involving high-J states}, year={2011}, journal={Molecular Physics}, volume={109}, pages={1925--1941}, doi={10.1080/00268976.2011.599343}, }
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RIS Citation
TY - JOUR ID - ma00800v AU - Ma, Q. AU - TIpping, R. H. AU - Lavrentieva, N. N. PY - 2011 TI - Pair identity and smooth variation rules applicable for the spectroscopic parameters of H2O transitions involving high-J states JA - Molec. Phys. JO - Molecular Physics VL - 109 SP - 1925 EP - 1941 DO - 10.1080/00268976.2011.599343 ER -
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